Upconversion Luminescence and Magnetic Turning of NaLuF 4

Fluorescent and magnetic bifunctional NaLuF4:Yb3+/Tm3+/Gd3+ nanocrystals were synthesized by the solvothermal method and subsequent surface modification. By changing the doping concentration of Gd3+, the shape, size, luminescent properties, and magnetic properties of the nanoparticles can be modulated. These NaLuF4:Yb3+/Tm3+/Gd3+ nanocrystals present efficient blue upconversion fluorescence and excellent paramagnetic property at room temperature. Based on the luminescence resonance energy transfer (LRET), upconversion nanoparticles (UCNPs) were confirmed to be an efficient fluorescent nanoprobe for detecting acriflavine. It is easy to derive the concentration of acriflavine from the Integral Intensity Ratio of Green (emission from acriflavine) to Blue (emission from UCNPs) fluorescent signals. Based on this upconversion fluorescent nanoprobe, the detection limit of acriflavine can reach up to 0.32 μg/mL

Differential responses of carbon-degrading enzyme activities to warming: implications for soil respiration

Extracellular enzymes catalyze rate‐limiting steps in soil organic matter decomposi-tion, and their activities (EEAs) play a key role in determining soil respiration (SR).Both EEAs and SR are highly sensitive to temperature, but their responses to cli-mate warming remain poorly understood. Here, we present a meta‐analysis on theresponse of soil cellulase and ligninase activities and SR to warming, synthesizingdata from 56 studies. We found that warming significantly enhanced ligninase activ-ity by 21.4% but had no effect on cellulase activity. Increases in ligninase activitywere positively correlated with changes in SR, while no such relationship was foundfor cellulase. The warming response of ligninase activity was more closely related tothe responses of SR than a wide range of environmental and experimental method-ological factors. Furthermore, warming effects on ligninase activity increased withexperiment duration. These results suggest that soil microorganisms sustain long‐term increases in SR with warming by gradually increasing the degradation of therecalcitrant carbon pool

Implementation of trait-based ozone plant sensitivity in the Yale interactive terrestrial biosphere model v1.0 to assess global vegetation damage

A major limitation in modeling global ozone (O3) vegetation damage has long been the reliance on empiri- cal O3 sensitivity parameters derived from a limited num- ber of species and applied at the level of plant functional types (PFTs), which ignore the large interspecific variations within the same PFT. Here, we present a major advance in large-scale assessments of O3 plant injury by linking the trait leaf mass per area (LMA) and plant O3 sensitivity in a broad and global perspective. Application of the new ap- proach and a global LMA map in a dynamic global veg- etation model reasonably represents the observed interspe- cific responses to O3 with a unified sensitivity parameter for all plant species. Simulations suggest a contemporary global mean reduction of 4.8 % in gross primary productivity by O3, with a range of 1.1 %–12.6 % for varied PFTs. Hotspots with damage > 10 % are found in agricultural areas in the eastern US, western Europe, eastern China, and India, accompanied by moderate to high levels of surface O3. Furthermore, we simulate the distribution of plant sensitivity to O3, which is highly linked with the inherent leaf trait trade-off strategies of plants, revealing high risks for fast-growing species with low LMA, such as crops, grasses, and deciduous trees

Convergence of Subtangent-Based Relaxations of Nonlinear Programs

Convex relaxations of functions are used to provide bounding information to deterministic global optimization methods for nonconvex systems. To be useful, these relaxations must converge rapidly to the original system as the considered domain shrinks. This article examines the convergence rates of convex outer approximations for functions and nonlinear programs (NLPs), constructed using affine subtangents of an existing convex relaxation scheme. It is shown that these outer approximations inherit rapid second-order pointwise convergence from the original scheme under certain assumptions. To support this analysis, the notion of second-order pointwise convergence is extended to constrained optimization problems, and general sufficient conditions for guaranteeing this convergence are developed. The implications are discussed. An implementation of subtangent-based relaxations of NLPs in Julia is discussed and is applied to example problems for illustration

Cloud-assisted tracking medical mobile robot for indoor elderly

Recently, research related to medical robots received considerable attention due to an increase in aging population. However, most of the existing approaches for designing medical robots have drawbacks in terms of lacking mobility, real-time monitoring of health conditions and emotional response. In this paper, we present a design for a cloud-assisted medical robot with mobility, which can remotely monitor and collect the parameters of human body. Moreover, the robot can upload this information to cloud and distribute it to a smart terminal in real-time. We construct the control and communication systems based on the main controller STM32 and WIFI, respectively. Further, user-friendly APPs are designed and a prototype of the mobile robot is built. Our proposed design approach can ensure the safety of elderly, reduce the burden of taking care of the elderly, and deal with emergency situations

Development and Characterization of Two Types of Surface Displayed Levansucrases for Levan Biosynthesis

Levan has wide applications in chemical, cosmetic, pharmaceutical and food industries. The free levansucrase is usually used in the biosynthesis of levan, but the poor reusability and low stability of free levansucrase have limited its large-scale use. To address this problem, the surface-displayed levansucrase in Saccharomyces cerevisiae were generated and evaluated in this study. The levansucrase from Zymomonas mobilis was displayed on the cell surface of Saccharomyces cerevisiae EBY100 using a various yeast surface display platform. The N-terminal fusion partner is based on a-agglutinin, and the C-terminal one is Flo1p. The yield of levan produced by these two whole-cell biocatalysts reaches 26 g/L and 34 g/L in 24 h, respectively. Meanwhile, the stability of the surface-displayed levansucrases is significantly enhanced. After six reuses, these two biocatalysts retained over 50% and 60% of their initial activities, respectively. Furthermore, the molecular weight and polydispersity test of the products suggested that the whole-cell biocatalyst of levansucrase displayed by Flo1p has more potentials in the production of levan with low molecular weight which is critical in certain applications. In conclusion, our method not only enable the possibility to reuse the enzyme, but also improves the stability of the enzyme

Transfer of Copper (Cu) in the Soil–Plant–Mealybug–Ladybird Beetle Food Chain

Copper, an essential trace element, is vital for living organisms’ survival; however, despite its importance, an excessive amount of this micro-nutrient can cause harmful effects to plants and animals. The present study investigates Cu bio-transfer across multi-trophic food chain comprising soil (spiked with various concentrations of Cu), eggplant (Solanum melongena), mealybug (Ferrisia virgata), and ladybird (Nephus ryuguus). Soils were spiked with Cu at rates of 0, 100, 200, 400, and 800 mg/kg (w/w). A dose-dependent increase in the levels of Cu in plant, mealybug, and ladybird was observed in response to Cu contents of soil. Different Cu amendment caused a significant reduction in the average root and shoot dry weights per plant as well as the average body weights of F. virgata and N. ryuguus. Our findings affirmed the importance of additional research to explain the processes involved in the bio-transfer of copper across the food chain

U-Th dating of a Paleolithic site in Guanyindong Cave, Guizhou Province, southwestern China

Guanyindong Cave in southwestern China has received considerable attention in the investigation of Paleolithic hominin origins and evolution in China, due to its rich archaeological finds composed of thousands of stone artifacts and a unique fauna with 23 species of mammalian fossils found. However, despite earlier extensive excavations and descriptive studies, debates still centre around the conflict between previous radiometric age data and evidence from biostratigraphic correlations. In this study, we carried out detailed field investigations and sampling, and obtained 35 U-Th dates on flowstone layers and other datable materials from the cave. The age results from materials in stratigraphic context provide a robust chronological framework of the cave. The data suggest that the deposition of Group B sediments and fossil assemblages widely distributed within the cave should have occurred after ~370 ka but before ~70 ka, with the bulk of the sediments and associated fossils laid down during 200–140 ka. Our new U-Th dates of in situ flowstone layers intercalated with one rhinoceros tooth and several other fossil fragments near the Hall at the centre of the cave constrain the deposition ages of these mammalian fossils to the period between 469 ± 37 and 336 ± 7 ka. Combined our U-Th data with recent OSL dates of Hu et al. (2019), we suggest that Group A sediments and associated fossils were likely deposited episodically from ca. 90 ka to 469 ± 37 ka ago, whilst the cave system framework took shape as we see today >340 ± 10 ka ago. Subsequently, the cave might have experienced several flooding and washout events, resulting in recycling and mixing of older sediments and fossils into younger sequences, a hypothesis consistent with tight clustering of both U-Th ages of speleothems in this study and the OSL dates of clastic sediments (Hu et al., 2019). This would reconcile the contradiction between the great antiquity of mammalian fossils inferred from biostratigraphic correlation and the much younger radiometric dates of materials in stratigraphic context, and explain the lack of technological advance despite an apparently long presence of the “Guanyindong culture”, as well as the presence of the Levallois technologies. In this regard, our U/Th age data, combined with other recent studies, have resulted in an improved understanding of Paleolithic hominid evolution and stone technologies in south China

Synthesis, Luminescent Properties and White LED Fabrication of Sm3+ Doped Lu2WMoO9

In this paper, Sm3+ doped Lu2W0.5Mo0.5O6, Lu2WMoO9, and Lu2(W0.5Mo0.5O4)3 materials were synthesized by using a two-step solid-state reaction method. The synthesized materials were characterized by X-ray diffraction (XRD) patterns, field emission scanning electronic micrograph (FE-SEM) pictures, photoluminescence (PL) excitation and emission spectra, and temperature-dependent emission intensities. Orange-reddish light could be observed from the phosphors under ultraviolet (UV) 365 nm light. The Sm3+ doped Lu2WMoO9 had enhanced PL intensities compared to the other two materials. The excitation, the energy transfer, the nonradiative relaxation, and the emission processes were illustrated by using schematic diagrams of Sm3+ in Lu2MoWO9. The optimal Sm3+ doping concentration was explored in the enhancing luminescence of Lu2WMoO9. By combing the Sm3+ doped Lu2WMoO9 to UV 365 nm chips, near white lighting emitting diode (W-LED) were obtained. The phosphor can be used in single phosphor-based UV W-LEDs